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This applet explores the c-axis projection of ammonium oxalate monohydrate,
a=8.035 b=10.309 c=3.795 Å P21 21 2.

Partly because the c-axis is relatively short, none of the atoms overlaps, so the molecular structure is clear in this projection. The panels and buttons below allow one to explore the relationship between each Fourier term, which is derived from the diffraction pattern, and its representation in real space.

Panels

Reciprocal Space

This panel shows a representation of the hk0 plane for ammonium oxalate. Click on a reflection to see the corresponding  Fourier term  in real space in the panel  "Fourier term".

Fourier Term

This panel shows the real space representation of the Fourier term given by the reflection denoted below the panel. Notice that when the F is negative (that is, the phase is pi), the Fourier term is negative (a trough) at the origin: when the F is a positive the Fourier term value at the origin is a crest.

Sum

This panel shows the accumulated sum of terms entered so far.

Buttons

Sum

After clicking Sum, all Fourier terms are summed.

Accum

Click this button repeatedly to add one term at a time. Those already included are set red in the reciprocal space panel.

Fit

This toggle button shows oxalate ions, ammonium ions and water molecules in the unit cell (and their symmetry equivalents).

Fs

This button launchs a new window that shows the F s.  There is a slider in the new window that can be used to change the resolution. The reflections used in the sum are then made bold, while those outside the limits are normal font.  A choice button at the bottom allows one to choose random phases, or random magnitudes. In this case the  Fused columns shows the F value used in the sum.

Restart

Clears all flags back to the default when the applet was started.

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