Equilibria
 

95.     The equilibrium point of the reaction

CH3.CO.COOH + NADH + H+ « CH3.CHOH.COOH + NAD+

is shifted to the left by:

1.        increasing the concentration of the enzyme catalysing the reaction
2.        decreasing the concentration of the enzyme catalysing the reaction
3.        increasing the concentration of CH3.CO.COOH
4.        decreasing the concentration of H+
5.        decreasing the concentration of NAD+

96.        The equilibrium point of the reaction

CH3.CH2OH + NAD+ « CH3.CHO + NADH + H+

is shifted to the right by:

1.        increasing the concentration of the enzyme catalysing the reaction
2.        decreasing the concentration of the enzyme catalysing the reaction
3.        increasing the concentration of H+
4.        decreasing the concentration of CH3.CHO
5.        decreasing the concentration of NAD+
 

97.        For the equilibrium reaction A « B + C, which one of the following is FALSE?

1.        The rate of the forward reaction is kf.[A]
2.        The rate of the backward reaction is kb.[B].[C]
3.        At equilibrium kf.[A] = kb.[B].[C] = 0
4.        The rate constant kf can be measured in min-1
5.        The rate constant kb can be measured in M-1 .min-1

98.     With regard to the reaction
  k-1  
A « B + C - heat
  k+1  
which one of the following is FALSE?

1.        The rate of the reaction from left to right is k+1×[A]
2.        The rate of the reaction from right to left is k-1×[B] × [C]
3.        At equilibrium k+1 = k-1
4.        The equilibrium constant Keq= [B]× [C]¸ [A] at equilibrium
5.        As temperature increases the equilibrium point moves to the right

99.       For the equilibrium
  k-1  
A + B « C + D + HEAT
  k+1  
which one of the following statements is FALSE?

1.        The rate of the forward reaction is represented by k+1.
2.        The equilbrium constant (Keq) = [C].[D]   at equilibrium.
                                                             [A].[B]
3.        An increase in temperature moves the equilibrium to the left.
4.        Addition of extra compound A results in an increase in products C and D.
5.        Removal of product D results in an increase in C.

100.     With regard to the reaction:
  k-1  
A + B+ « P + Q + H+
  k+1  
which one of the following is FALSE?:

1.        The rate of the forward reaction is k+1×[A]× [B+]
2.        The rate of the back reaction is k-1×[P]× [Q]× [H+]
3.        As pH increases the concentrations of P and Q at equilibrium increase
4.        The equilibrium constant Keq = k+1-k-1
5.        The units of Keq are for example nmol/l

101.     With regard to the reaction:
  k-1  
A + B + H+ « P + Q
  k+1  
which one of the following is FALSE?:

1.        The rate of the forward reaction is k+1×[A]× [B]× [H+]
2.        The rate of the back reaction is k-1×[P]× [Q]
3.        At equilibrium the rates of the forward and back reactions are equal
4.        The equilibrium constant Keq = [P]× [Q]/[A]× [B]× [H+] at equilibrium
5.        As pH increases the concentrations of P and Q at equilibrium increase
 
 

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